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有机化学
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有机化学 ›› 2007, Vol. 27 ›› Issue (12): 1582-1585. 上一篇    下一篇

研究简报

纯水中金属钕诱发芳香醛烯丙基化反应的研究

边延江*，胡晓红，王虎   

  1. (河北廊坊师范学院化学系 廊坊 065000)
  • 收稿日期:2006-09-21 修回日期:2007-05-30 发布日期:2007-12-04
  • 通讯作者: 边延江

Allylation Reactions of Aromatic Aldehydes with Neodymium in Water

BIAN Yan-Jiang*, HU Xiao-Hong, WANG Hu   

  1. (Department of Chemistry, Langfang Normal College, Langfang 065000)
  • Received:2006-09-21 Revised:2007-05-30 Published:2007-12-04
  • Contact: BIAN Yan-Jiang

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1004

被引次数

8 | 1

在Nd-SnCl2-H2O体系中, 用烯丙基溴超声诱发下进行了一系列芳香醛的烯丙基反应, 室温反应50～60 min得76%～93%烯丙基化产物; 而不用超声波时同样体系中搅拌3～4 h高烯丙基醇产率为30%～86%. 该方法时间短、产率高、环境友好.

关键词: 羰基化合物, 烯丙基化, 钕, 水, 二氯化锡

The allylation reactions of aldehydes with allyl bromide were carried out in 76%～93% yields with Nd-SnCl2-H2O under ultrasound irradiation at room temperature for 50～60 min. The reactions in the same system gave homoallylic alcohols in 30%～86% yields without ultrasound irradiation under stirring for 3～4 h. The main advantages of the present procedure are shorter reaction time, higher yield and environmentally benign way.

Key words: allylation, water, neodymium, tin dichloride, carbonyl compound