有机化学 ›› 1989, Vol. 9 ›› Issue (4): 337-340. 上一篇    下一篇

研究论文

高碳三级硫醇的简便合成法

曹正白;陈勇;郭松山;陈克潜   

  1. 苏州大学化学系
  • 发布日期:1989-08-25

A facile method for the synthesis of long chain alkyl tertiary mercaptans

CAO ZHENGBAI;CHEN YONG;GUO SONGSHAN;CHEN KEQIAN   

  • Published:1989-08-25

本文提出了一种合成高碳三级硫醇的简便方法, 具有方便和高得率的特点, 并由对甲苯磺酸和硫脲与叔醇反应并用氢氢化钠水解制备了七个三级硫醇。

关键词: 硫醇, 硫脲, 高级烷烃 P, 醇, 苯磺酸 P, 甲苯 P, 拉曼光谱法

A facile method for the synthesis of long chain alkyl tertiary mercaptans is reported. This method proves to be more convenient and offers high yield. Seven tertiary mercaptans have been prepared by the reaction of p-toluenesulfonic acid and thiourea with tertiary alcs. followed by hydrolysis of the S-alkyl isothiouronium salts with sodium hydroxide.

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