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有机化学
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有机化学 ›› 2008, Vol. 28 ›› Issue (2): 256-260. 上一篇    下一篇

研究论文

MCM-41负载硫醚钯配合物的合成及其催化芳基卤化物的羰基化性能

余腊妹a，许秋华b，蔡明中*,a   

  1. (a江西师范大学化学化工学院 南昌 330022)
    (b南昌航空工业学院环境与化学工程学院 南昌 330063)
  • 收稿日期:2007-02-22 修回日期:2007-08-10 发布日期:2008-02-01
  • 通讯作者: 蔡明中

Synthesis of MCM-41-Supported Thioether Palladium Complex and Its Catalytic Properties in Carbonylation of Aryl Halides

YU La-Meia,XU Qiu-Huab,CAI Ming-Zhong*,a   

  1. (a School of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022)
    (b School of Environmental and Chemical Engineering, Nanchang Institute of Aeronautical Technology, Nanchang 330063)
  • Received:2007-02-22 Revised:2007-08-10 Published:2008-02-01
  • Contact: CAI Ming-Zhong

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734

被引次数

6

γ-(β-氰乙硫基)丙基三乙氧基硅烷依次用纳米介孔分子筛(MCM-41)固载、与氯化钯反应, 合成了MCM-41负载硫醚钯配合物. 该新型负载钯配合物是芳基卤化物的羰基化反应的有效催化剂, 为各种取代的N-苯基苯甲酰胺、苯甲酸丁酯的合成提供了方便实用的新途径.

关键词: 负载钯催化剂, MCM-41, 硫醚钯配合物, 芳基卤化物, 羰基化

MCM-41-supported thioether palladium complex has been prepared via immobilization of 3-(2-cyanoethylsulfanyl)propyltriethoxysilane on MCM-41, followed by reacting with palladium chloride. The complex is an efficient catalyst for Heck carbonylation of aryl halides with aniline or n-butyl alcohol under atmospheric pressure of carbon monoxide. A variety of substituted N-phenylbenzamides and n-butyl benzoates were prepared. Importantly, the complex can be recovered and reused without loss of activity.

Key words: MCM-41, supported palladium catalyst, thioether palladium complex, aryl halide, carbonylation