有机化学 ›› 1998, Vol. 18 ›› Issue (1): 50-53. 上一篇    下一篇

研究论文

氨基苯甲酸三苯基锡酯的酰化和缩合反应及产物的热分析研究

路军;杨秉勤;马怀让;陈景元   

  1. 西北大学化学系;咸阳师范专科学校化学系
  • 发布日期:1998-02-25

Acylation and condensation of triphenyltin 4-aminobenzoate and thermoanalysis of their products

LU JUN;YANG BINGQIN;MA HUAIRANG;CHEN JINGYUAN   

  • Published:1998-02-25

4-氨基苯甲酸三苯基锡酯与酸酐和醛进行酰化和缩合反应,合成了10个N-三苯基锡基胺羰基苯甲酸和亚胺类化合物。热分析表明亚胺10分子中Sn-Ph键比Sn-Bu键稳定。

关键词: 酰化, 羰基化合物, 有机锡化合物, 亚胺络合物, 缩合反应, 醛, 酸酐, 热分析, 苯甲酸 P, 苯基酯

Ten organotin compounds have been synthesized by acylation and condensation of triphenyltin 4-aminobenzoate with organic anhydrides and aromatic aldehydes. The thermoanalysis of binuclear organotin imine (10) demonstrates that the Sn-Ph bond is more stable than the Sn-Bu one.

Key words: ACYLATION, ORGANO TIN COMPOUNDS, CARBONYL COMPOUNDS, THERMAL ANALYSIS, IMINO COMPLEX, ACID ANHYDRIDE, ALDEHYDES, BENZENECARBOXYLIC ACID P, PHENYLESTER, CONDENSATION REACTION

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