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有机化学
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有机化学 ›› 2006, Vol. 26 ›› Issue (12): 1613-1622.    下一篇

综述与进展

过渡金属不对称催化氧杂苯并降冰片烯开环反应的研究进展

杨定乔*，韩英锋   

  1. (华南师范大学化学与环境学院 广州 510006)
  • 收稿日期:2006-05-20 修回日期:2006-01-23 发布日期:2006-11-21
  • 通讯作者: 杨定乔

Progress in Transition Metal-Catalyzed Asymmetric Ring Opening Reactions of Oxabenzonorbornadienes

YANG Ding-Qiao*,HAN Ying-Feng   

  1. (School of Chemistry and Environment, South China Normal University, Guangzhou 510006)
  • Received:2006-05-20 Revised:2006-01-23 Published:2006-11-21
  • Contact: YANG Ding-Qiao

PDF

1793

被引次数

7

综述了近年来过渡金属不对称催化氧杂苯并降冰片烯开环反应的研究进展, 包括钯催化、镍催化、铜催化和铑催化四部分内容, 并对部分反应的机理进行了介绍.

关键词: 不对称开环反应, 过渡金属催化, 氧杂苯并降冰片烯

The recent progress in transition metal-catalyzed asymmetric ring opening (ARO) reactions of oxabenzonorbornadienes including the Pd-, Ni-, Cu- and Rh-catalyzed ARO is reviewed. Moreover, the catalytic possible mechanisms are discussed.

Key words: transition metal-catalyzed, oxabenzonorbornadiene, asymmetric ring opening reaction