有机化学 ›› 2013, Vol. 33 ›› Issue (05): 1096-1099.DOI: 10.6023/cjoc2012012049 上一篇    下一篇

研究简报

二苯基二硒醚催化双氧水氧化环己烯合成1,2-环己二醇

俞磊a,b,c, 王俊b, 陈天b, 丁克鸿c, 潘毅a   

  1. a 南京大学化学化工学院 南京 210093;
    b 扬州大学化学化工学院 扬州 225002;
    c 江苏扬农化工集团有限公司 扬州 225009
  • 收稿日期:2012-12-30 修回日期:2013-01-16 发布日期:2013-01-25
  • 通讯作者: 俞磊,yulei@yzu.edu.cn E-mail:yulei@yzu.edu.cn
  • 基金资助:

    国家自然科学基金(No. 21202141)、江苏省高校优势学科项目、江苏省环境材料与工程重点实验室开放基金(Nos. K11024, K090030)资助项目.

Access to Cyclohexane-1,2-diol through the Diphenyldiselenide Catalyzed Oxidation of Cyclohexene by Hydrogen Peroxide

Yu Leia,b,c, Wang Junb, Chen Tianb, Ding Kehongc, Pan Yia   

  1. a School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093;
    b School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002;
    c Jiangsu Yangnong Chemical Engineering Co. Ltd., Yangzhou 225009
  • Received:2012-12-30 Revised:2013-01-16 Published:2013-01-25
  • Supported by:

    Project supported by the National Natural Science Fundation of China (No. 21202141), the Priority Academic Program Development of Jiangsu Higher Education Institutions, the Opening Foundation of the Key Laboratory of Environmental Materials and Engineering of Jiangsu Province (Nos. K11024, K090030).

在二苯基二硒醚催化下, 双氧水可氧化环己烯, 高转化率与选择性地生成1,2-环己二醇. 1,2-环己二醇是重要的化工产品. 与传统金属催化剂相比, 硒化合物催化剂有着价格较低、对环境危害小等优点. 这一合成方法还具有清洁、高原子经济等优点. 因此, 该反应具有很高的应用价值.

关键词: 硒, 催化, 绿色化学, 环己二醇, 氧化

The diphenyldiselenide catalyzed oxidation of cyclohexene by hydrogen peroxide led to cyclohexane-1,2-diol with high conversion and selectivity. Compared with traditional metal catalyst, selenium catalysts are cheaper and less harmful to environment. This synthetic method is also clean and highly atom-economic. Therefore, this reaction is highly applicable.

Key words: selenium, catalysis, green chemistry, cyclohexane-1,2-diol, oxidation