手性双金属催化剂及其在不对称催化反应中的应用

doi:10.6023/cjoc201301032

摘要/Abstract

多金属催化过程是生命体实现新陈代谢的主要方式之一, 在自然界广泛存在. 多金属催化剂相比于单金属催化剂, 具有更加高的反应活性和对映选择性, 近年来其设计与应用已经成为有机化学的研究热点之一. 综述了近年来不同种类的具有代表性的双金属催化剂的研究进展, 包括双杂金属和双核同金属, 介绍了双金属催化剂的反应类型、反应机理以及发展现状, 提出了今后的研究重点与发展趋势.

关键词: 不对称催化, 多金属, 双核同金属催化剂, 双杂金属催化剂

Polymetallic catalytic process is the main metabolic way of life, which is widely observed in nature. Compared to the mono-metal catalysts, the designs and applications of polymetallic catalysts with high reactivity and enantioselectivity have been a hot research topic in organic chemistry recently. This review covers the recent research process on representative types of bimetallic catalysts, including hetero-bimetallic catalysts and dinuclear homometal catalysts, their reaction mechanisms and developments. Moreover, potentially development of this area is also discussed.

Key words: asymmetric catalysis, polymetallic, dinuclear homometal catalyst, hetero-bimetallic catalyst

引用此文

李昆, 杨国强, 刘媛媛, 张万斌. 手性双金属催化剂及其在不对称催化反应中的应用[J]. 有机化学, 2013, 33(04): 749-759.

Li Kun, Yang Guoqiang, Liu Yuanyuan, Zhang Wanbin. Chiral Polymetallic Catalysts and Their Applications in Asymmetric Catalysis[J]. Chin. J. Org. Chem., 2013, 33(04): 749-759.

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