有机化学 ›› 2017, Vol. 37 ›› Issue (12): 3130-3145.DOI: 10.6023/cjoc201704050 上一篇    下一篇

综述与进展

催化炔烃马氏水合反应研究进展

杨璐, 徐彩霞   

  1. 石河子大学化学化工学院 新疆兵团化工绿色过程重点实验室 石河子 832003
  • 收稿日期:2017-04-29 修回日期:2017-07-07 发布日期:2017-08-11
  • 通讯作者: 徐彩霞 E-mail:xcxia@shzu.edu.cn
  • 基金资助:

    兵团应用基础研究计划(No.2015AG001)和石河子大学高层次人才启动计划(No.RCZX201405)资助项目.

Advances in the Catalytic Markovnikov Hydration of Alkynes toward Ketones

Yang Lu, Xu Caixia   

  1. Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, School of Chemistry and Chemical En-gineering, Shihezi University, Shihezi 832003
  • Received:2017-04-29 Revised:2017-07-07 Published:2017-08-11
  • Contact: 10.6023/cjoc201704050 E-mail:xcxia@shzu.edu.cn
  • Supported by:

    Project supported by the Applied Basic Research Program of Bingtuan (No. 2015AG001) and the High-Level Talent Scientific Research Project of Shihezi University (No. RCZX201405).

羰基是有机合成中的重要骨架结构单元,而催化炔烃马氏水合为酮来构建羰基是环境友好、具有100%原子经济性的反应,也是近年来有机化学研究的热点之一.按催化剂分类总结了炔烃水合反应的研究进展以及催化炔烃水合反应的机理,并对今后催化炔烃水合反应的发展方向进行了展望.

关键词: 炔烃, 马氏水合, 催化, 酮, 机理

Carbonyl group is one of the important building blocks in organic synthesis. The catalytic Markovnikov hydration of alkynes is an eco-friendly reaction with 100% atom economy to construct carbonyl compounds, and is one of hot spots of organic chemistry over recent years. Research progress concerning catalytic hydration of alkynes to ketones on the view of the types of catalysts, and catalytic mechanisms are concluded. Finally, the further development and challenge of catalytic hydration of alkynes are dis-cussed.

Key words: alkyne, Markovnikov hydration, catalytic, ketone, mechanism