有机化学 ›› 2019, Vol. 39 ›› Issue (3): 617-624.DOI: 10.6023/cjoc201809030 上一篇    下一篇

综述与进展

亚磺酸钠参与合成含硫化合物研究进展

黄国保, 李秀英, 罗金荣, 罗志辉, 谭明雄   

  1. 玉林师范学院 广西农产资源化学与生物技术重点实验室 玉林 537000
  • 收稿日期:2018-09-25 修回日期:2018-10-28 发布日期:2018-11-26
  • 通讯作者: 罗志辉, 谭明雄 E-mail:Lzhui_1980@163.com;tanmx00@163.com
  • 基金资助:

    国家自然科学基金(Nos.21761033,21565028)、广西自然科学基金(No.2017GXNSFBA198211)以及玉林师范学院科研(No.2018YJKY36)资助项目.

Recent Progress on Synthesis of Sulfur Compounds by Sodium Sulfinates

Huang Guobao, Li Xiuying, Luo Jinrong, Luo Zhihui, Tan Minxiong   

  1. Guangxi Key Laboratory of Agricultural Resources Chemistry and Biotechnology, Yulin Normal University, Yulin 537000
  • Received:2018-09-25 Revised:2018-10-28 Published:2018-11-26
  • Contact: 10.6023/cjoc201809030 E-mail:Lzhui_1980@163.com;tanmx00@163.com
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21761033, 21565028), the Natural Science Foundation of Guangxi (No. 2017GXNSFBA198211), and the Yulin Normal University Research Grant (No. 2018YJKY36).

亚磺酸钠(RSO2Na)性质稳定、合成简单、价格低廉,在有机合成化学领域被广泛应用.综述了最近五年来亚磺酸钠在合成含硫化合物反应中的最新研究进展.分别叙述了其在有机反应中构建S-C键、S-杂键(S-S键、S-N键以及S-P键)的底物适应范围和反应机理,为今后亚磺酸钠的在有机合成中的应用提供参考.

关键词: 亚磺酸钠, 含硫化合物, 反应机理

Sodium sulfinates (RSO2Na) is a kind of reagents with stable properties, simple synthesis and low price, which has been widely used in the field of organic synthesis chemistry. The recent progress (2014~2018) on synthesis of sulfur compounds by sodium sulfinates is summarized. In addition, the organic reactions on the building of S-X (S-S, S-N and S-P bond) and other types of reactions are described respectively, with their scope of substrates and reaction mechanism. It is hoped that this review can be referred to the future application in organic synthesis of sodium sulfinates.

Key words: sodium sulfiniates, sulfur compounds, reaction mechanism