有机化学 ›› 2022, Vol. 42 ›› Issue (8): 2568-2573.DOI: 10.6023/cjoc202202008 上一篇    下一篇

研究论文

可见光诱导甲酸盐参与的烯烃氢羧化反应

黄燕, 张谦, 詹乐武, 侯静*(), 李斌栋*()   

  1. 南京理工大学化学与化工学院 南京 210094
  • 收稿日期:2022-02-08 修回日期:2022-04-11 发布日期:2022-04-22
  • 通讯作者: 侯静, 李斌栋
  • 作者简介:
    共同第一作者
  • 基金资助:
    国家自然科学基金(21901118); 江苏省自然科学基金(BK20190430); 重点高校基础科研业务费专项资金(30921011206)

Hydrocarboxylation of Alkenes with Formate Salts via Photocatalysis

Yan Huang, Qian Zhang, Lewu Zhan, Jing Hou(), Bindong Li()   

  1. College of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094
  • Received:2022-02-08 Revised:2022-04-11 Published:2022-04-22
  • Contact: Jing Hou, Bindong Li
  • About author:
    These authors contributed equally to this work.
  • Supported by:
    National Natural Science Foundation of China(21901118); Natural Science Foundation of Jiangsu Province(BK20190430); Fundamental Research Funds for the Central Universities(30921011206)

发展了一种温和条件下以甲酸盐作为还原剂和羰基来源的β-选择性烯烃氢羧化反应. 利用该方法, 一系列的烯烃能够被有效地转化为高价值的羧酸产品. 该方法具备催化剂用量小、官能团耐受性好、易于放大等特点.

关键词: 烯烃, 氢羧化, 光催化, 二氧化碳自由基负离子, 甲酸盐

A transition-metal-free β-selective hydrocarboxylation of alkenes under mild conditions has been developed using a formate salt as the reductant, carbonyl source. A broad range of alkenes were compatible with this method and can be efficiently converted into value-added carboxylic acid products. This method also features low catalyst loading, good functional group tolerance, and easy scalability.

Key words: alkenes, hydrocarboxylation, photocatalysis, carbon dioxide radical anion, formate salt