光化学转化二氧化碳合成羧酸化合物的研究进展

doi:10.6023/cjoc202405004

摘要/Abstract

光化学反应以洁净、节能、节约为目标,为合成化学提供了新途径和新方法,成为现代有机合成化学中非常活跃的研究领域之一。二氧化碳(CO₂)由于其无毒、廉价易得、储量丰富且可循环再生等特点,是合成化学中理想的C1合成子。近年来,光催化促进的CO₂向羧酸化合物的转化得到了快速发展,为羧酸化合物的制备提供了一种温和并高效合成方法。综述了光催化转化CO₂合成羧酸化合物的合成方法研究进展,并对其部分反应机理做了相应的阐述。

关键词: 二氧化碳, 光催化, 羧基化

The pursuit of cleanliness, energy efficiency, and resource preservation through photochemical reactions has led to the emergence of novel pathways and methodologies in synthetic chemistry, rendering it one of the most dynamic research domains within modern organic synthesis. Carbon dioxide (CO₂), owing to its non-toxic, cost-effective, abundant, and recyclable attributes, serves as an optimal C1 precursor in synthetic chemistry. Recent years have witnessed rapid advancements in the photochemical conversion of CO₂ into carboxylic acid compounds, offering a gentle and highly efficient synthetic approach for their production. This review provides an overview of the research progress on the synthesis methodologies of carboxylic acid compounds through photochemical CO₂ conversion, while also elucidating certain associated reaction mechanisms.

Key words: carbon dioxide, photocatalysis, carboxylation

引用此文

袁盼锋, 朱灿明, 孟庆元. 光化学转化二氧化碳合成羧酸化合物的研究进展[J]. 有机化学, doi: 10.6023/cjoc202405004.

Pan-Feng Yuan, Can-Ming Zhu, Qing-Yuan Meng. Advances in the synthesis of carboxylic acid by photochemical conversion of CO₂[J]. Chinese Journal of Organic Chemistry, doi: 10.6023/cjoc202405004.

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