Application of Oxazoline Ligands in Palladium-Catalyzed Asymmetric Oxidative Functionalization of Alkenes

doi:10.6023/cjoc201603010

Chin. J. Org. Chem. ›› 2016, Vol. 36 ›› Issue (8): 1797-1804.DOI: 10.6023/cjoc201603010 Previous Articles Next Articles

REVIEW

噁唑啉类配体在钯催化烯烃的不对称氧化官能化反应中的应用

刘小建^a, 陈品红^b, 吴范宏^a

a 上海应用技术学院化学与环境工程学院上海 201418;
b 中国科学院上海有机化学研究所金属有机化学国家重点实验室上海 200032

收稿日期:2016-03-08 修回日期:2016-04-22 发布日期:2016-05-03
通讯作者: 陈品红, 吴范宏 E-mail:pinhongchen@sioc.ac.cn;wfh@sit.edu.cn
基金资助:
国家自然科学基金（No. 21472217）资助项目.

Application of Oxazoline Ligands in Palladium-Catalyzed Asymmetric Oxidative Functionalization of Alkenes

Liu Xiaojian^a, Chen Pinhong^b, Wu Fanhong^a

a School of Chemical and Enviromental Engineering, Shanghai Institute of Technology, Shanghai 201418;
b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032

Received:2016-03-08 Revised:2016-04-22 Published:2016-05-03
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21472217).

Palladium-catalyzed oxidative functionalization of alkenes is one of the most powerful tools to synthesize complicated molecules. The related asymmetric reactions have received much attention. Due to the oxidative condition, however, compatible chiral ligand is quite limited. Recently, oxazoline-type ligand was applied in these reactions and exhibited good to excellent enantioselectivity. In this review, the recent studies on palladium-catalyzed asymmetric oxidative functionalization of alkenes with oxazoline ligands were summarized.

Key words: oxazoline, palladium, alkenes, asymmetric catalysis

Cite this article

Liu Xiaojian, Chen Pinhong, Wu Fanhong. Application of Oxazoline Ligands in Palladium-Catalyzed Asymmetric Oxidative Functionalization of Alkenes[J]. Chin. J. Org. Chem., 2016, 36(8): 1797-1804.

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噁唑啉类配体在钯催化烯烃的不对称氧化官能化反应中的应用

Application of Oxazoline Ligands in Palladium-Catalyzed Asymmetric Oxidative Functionalization of Alkenes

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