Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (12): 3130-3145.DOI: 10.6023/cjoc201704050 Previous Articles     Next Articles



杨璐, 徐彩霞   

  1. 石河子大学化学化工学院 新疆兵团化工绿色过程重点实验室 石河子 832003
  • 收稿日期:2017-04-29 修回日期:2017-07-07 发布日期:2017-08-11
  • 通讯作者: 徐彩霞
  • 基金资助:


Advances in the Catalytic Markovnikov Hydration of Alkynes toward Ketones

Yang Lu, Xu Caixia   

  1. Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, School of Chemistry and Chemical En-gineering, Shihezi University, Shihezi 832003
  • Received:2017-04-29 Revised:2017-07-07 Published:2017-08-11
  • Contact: 10.6023/cjoc201704050
  • Supported by:

    Project supported by the Applied Basic Research Program of Bingtuan (No. 2015AG001) and the High-Level Talent Scientific Research Project of Shihezi University (No. RCZX201405).

Carbonyl group is one of the important building blocks in organic synthesis. The catalytic Markovnikov hydration of alkynes is an eco-friendly reaction with 100% atom economy to construct carbonyl compounds, and is one of hot spots of organic chemistry over recent years. Research progress concerning catalytic hydration of alkynes to ketones on the view of the types of catalysts, and catalytic mechanisms are concluded. Finally, the further development and challenge of catalytic hydration of alkynes are dis-cussed.

Key words: alkyne, Markovnikov hydration, catalytic, ketone, mechanism