Chin. J. Org. Chem. ›› 1995, Vol. 15 ›› Issue (1): 57-60. Previous Articles     Next Articles

Original Articles

1-硫代-1-磷杂-2,6,7-三氧杂双环[2.2.2]辛烷基-4-亚甲基硫醚及其亚砜的合成

李玉桂;王新龙;朱雪峰;周汉杰   

  1. 南开大学元素有机化学研究所
  • 发布日期:1995-02-25

Study on the synthesis of 1-sulfur-1-phospha-2,6, 7-trioxzbicyclo [2.2.2] octyl-4-methyl thioethers and its sulfoxides

LI YUGUI;WANG XINLONG;ZHU XUEFENG;ZHOU HANJIE   

  • Published:1995-02-25

Nine new thioethers of caged bicyclic thiophosphates 3a~i were propared by Williamson reaction. Oxidation of the thioethers 3b and 3c gave the corresponding sulfoxide 4b and 4c which containning one chiral sulfur atom. The stereochemistry of the slfoxide was also discussed.

Key words: SULFOXIDE, SULFUR ETHER, SYNTHESIS, BICYCLIC PHOSPHATES

CLC Number: