Chin. J. Org. Chem. ›› 1997, Vol. 17 ›› Issue (5): 442-445. Previous Articles     Next Articles

Original Articles

三异丙氧钐催化下醇的选择性乙酰化反应

付晓林;吴世晖   

  1. 复旦大学化学系
  • 发布日期:1997-10-25

Selective acetylation of alcohols catalyzed by tri-2-propoxide samarium

FU XIAOLIN;WU SHIHUI   

  • Published:1997-10-25

This paper reports a simple, mild and convenient method for selective acetylation of primary alcohols in the presence of secondary alcohols using ethyl acetate as acetylated agent. These reactions are catalyzed by tri-2-propoxide samarium (5%) with good to excellent yields.

Key words: SAMARIUM COMPOUNDS, REACTION SELECTIVITY, ACETYLATION, ALCOHOL, ORGANIC REAGENTS, ETHYL ACETATE, ISOPROPYL GROUP, CATALYSIS

CLC Number: