Synthesis, properties and structure of the halides of  (Z)-3- triarylstannyl-1, 1-diphenyl-2-propenyl-1-ol

Chin. J. Org. Chem. ›› 1998, Vol. 18 ›› Issue (5): 447-451. Previous Articles Next Articles

Original Articles

Ph~2C(OH)CH=CHSnAr~3的卤化物的合成、表征和性质

朱东升;戴慧聪;单希林;傅芳信;潘华德

东北师范大学化学系.长春(130024);大庆石油学院化工系

发布日期:1998-10-25

Synthesis, properties and structure of the halides of (Z)-3- triarylstannyl-1, 1-diphenyl-2-propenyl-1-ol

Zhu Dongsheng;Dai Huicong;Shan Xilin;Fu Fangxin;Pan Huade

NE Normal Univ, Dept Chem.Changchun(130024)

Published:1998-10-25

Abstract

The reaction of the compound (Z)-3-triarylstannyl-1, 1-diphenyl- 2- propenyl-1-ol with ICl, Br~2, I~2 formed organotin halides, which reacted with KOH to form organotin oxide or hydroxide. The complexes were obtained by the organotin halides with three ligandrs (2, 2'- bipyridyl, 1, 10-phenanthroline, 8-hydroxyquinoline). The seventeen new compounds were characterized by means of elemental analysis, IR and ^1H NMR. Studied on the properties of the halides.

Key words: STRUCTURE CHARACTERISTICS, TIN COMPLEX, HALOGEN, PROPENOL P, SYNTHESIS, HALOGEN COMPLEX, METAL HALIDE, ORGANO TIN COMPOUNDS

CLC Number:

O627

Cite this article

Zhu Dongsheng;Dai Huicong;Shan Xilin;Fu Fangxin;Pan Huade. Synthesis, properties and structure of the halides of (Z)-3- triarylstannyl-1, 1-diphenyl-2-propenyl-1-ol[J]. Chin. J. Org. Chem., 1998, 18(5): 447-451.

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Ph~2C(OH)CH=CHSnAr~3的卤化物的合成、表征和性质

Synthesis, properties and structure of the halides of (Z)-3- triarylstannyl-1, 1-diphenyl-2-propenyl-1-ol

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