The quantified effecting of alcohol solvent on the  carbonyl (C=O) ultraviolet absorption

Chin. J. Org. Chem. ›› 1999, Vol. 19 ›› Issue (1): 77-80. Previous Articles Next Articles

Original Articles

醇溶剂对羰基(C=O)紫外吸收的定量影响

文彬;曹晨忠

湘潭师范学院化学系.湖南(411100)

发布日期:1999-02-25

The quantified effecting of alcohol solvent on the carbonyl (C=O) ultraviolet absorption

Wen Bin;Cao Chenzhong

Xiangtan Normal College, Department of Chemistry.Xiangtan(411100)

Published:1999-02-25

Abstract

Using a series of alcohols as solvents, the ultraviolet absorption energy (ΔE) values of carbonyl (C=O) for acetone and cyclohexanone were determined. The relations between those ΔE values and the molecular structure of solvent alcohols were discussed. The obtained results showed that there is a good linear relation between the ΔE value and the alkyl polarizability effect index PEI value of alcohol molecule, that is ΔE=a+bPEI.

Key words: CARBONYL COMPOUNDS, SOLVENTS, CYCLOHEXANONE, ULTRAVIOLET SPECTROPHOTOMETRY, ACETONE, ALCOHOL

CLC Number:

O621

Cite this article

Wen Bin;Cao Chenzhong. The quantified effecting of alcohol solvent on the carbonyl (C=O) ultraviolet absorption[J]. Chin. J. Org. Chem., 1999, 19(1): 77-80.

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醇溶剂对羰基(C=O)紫外吸收的定量影响

The quantified effecting of alcohol solvent on the carbonyl (C=O) ultraviolet absorption

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