Chin. J. Org. Chem. ›› 2001, Vol. 21 ›› Issue (11): 933-943. Previous Articles     Next Articles

SpirOP, DPAMPP和不对称催化反应

蒋耀忠;宓爱巧;邓金根;龚流柱   

  1. 中国科学院成都有机化学研究所.成都(610041)
  • 发布日期:2001-11-25

SpirOP, DPAMPP and asymmetric catalytic reaction

Jiang Yaozhong;Mi Aiqiao;Deng Jingen;Gong Liuzhu   

  1. Chengdu Inst Organ Chem, CAS.Chengdu(610041)
  • Published:2001-11-25

Novel chiral ligands, SpirOP and DPAMPP have been synthesized and applied in Rhodium-catalyzed asymmetric hydrogenation of dehydroamino acid derivatives with high catalytic activities and excellent enantioselectivities (up to 99% ee).

Key words: CHIRAL REAGENT, DEHYDROGENATION REACTION, RHODIUM COMPLEX, AMINO ACID, CATALYST, ORGANO PHOSPHORUS COMPOUNDS, LIGANDS, SPIRO COMPOUNDS, CATALYTIC REACTION

CLC Number: