Chinese Journal of Organic Chemistry ›› 2004, Vol. 24 ›› Issue (6): 591-599. Previous Articles     Next Articles

过渡金属催化的1,6-烯炔环异构化反应

童晓峰, 张兆国*   

  1. 中国科学院上海有机化学研究所 金属有机化学国家重点实验室 上海 200032
  • 收稿日期:2003-08-27 修回日期:2003-10-31 接受日期:2003-10-31 发布日期:2022-09-21
  • 通讯作者: *E-mail: zhaoguo@mail.sioc.ac.cn

Cycloisomerization of 1,6-Enynes Catalyzed by Transition Metals

TONG, Xiao-Feng, ZHANG, Zhao-Guo*   

  1. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences, Shanghai 200032
  • Received:2003-08-27 Revised:2003-10-31 Accepted:2003-10-31 Published:2022-09-21

The behavior of 1,6-enynes in the presence of transition metal catalysts has been extensively studied. 1,6-Enyne cycloisomerization reactions catalyzed by transition metals and three different reaction pathways, namely cyclometalation, halorhodation and π-allyl rhodium route, divided according to the reaction mechanism are summarized and discussed.

Key words: 1,6-enyne, transition metal, catalysis, cycloisomerization