Chin. J. Org. Chem. ›› 2009, Vol. 29 ›› Issue (04): 504-516. Previous Articles     Next Articles

Review

联三吡啶配体及其衍生物合成进展

苑嗣纯* ; 王惠川; 陈海波   

  1. (a北京农学院基础科学系 北京 102206)
    (b北京大学化学与分子工程学院 教育部生物有机化学与分子工程重点实验室 北京 100871)
  • 收稿日期:2008-06-13 修回日期:2008-07-03 发布日期:2009-04-20
  • 通讯作者: 苑嗣纯

Advances in the Synthesis of Terpyridine Ligand and Its Derivatives

Yuan, Sichun*; Wang, Huichuan ; Chen, Haibo   

  1. (a Department of Fundamental Science, Beijing University of Agriculture, Beijing 102206)
    (b Key Laboratory of Bioorganic and Molecular Engineering, Ministry of Education, College of Chemistry and
    Molecular Engineering, Peking University, Beijing 100871)

  • Received:2008-06-13 Revised:2008-07-03 Published:2009-04-20
  • Contact: Yuan, Sichun

Metal-ligand coordination is one of the most important interactions used in supramolecular chemistry. Oli-gopyridine ligands can coordinate with many transition metal ions to form stable complexes with interesting magnetic, photophysical and electrochemical properties, so the synthetic methodologies for terpyridine ligands and their transition metal complexes have been attracting considerable attention. This review summarizes the synthetic methodologies for terpyridine and its derivatives. The reactions are mainly classified into two kinds: ring-forming condensation and transition metals catalyzed cross-coupling. Mean-while, some other methods are also emphasized and a number of representative examples are selected to il-lustrate the ligand structures and synthetic methods.

Key words: terpyridine ligand, synthesis, ring-forming condensation reaction, cross-coupling reaction