Chin. J. Org. Chem. ›› 2010, Vol. 30 ›› Issue (05): 760-763. Previous Articles     Next Articles

Notes

一种新的含硫手性β-氨基醇配体的合成与表征

赵文献*,郑昕,李高伟,郭保国,徐海云   

  1. (商丘师范学院化学系 商丘师范学院有机新材料合成重点实验室 商丘 476000)
  • 收稿日期:2009-08-19 修回日期:2009-12-31 发布日期:2010-01-29
  • 通讯作者: 赵文献 E-mail:zhwx195812@yahoo.com.cn

Synthesis and Characterization of a Novel Sulfur-Containing Chiral β-Amino Alcohol Ligand

ZHAO Wen-Xian, ZHENG Xin, LI Gao-Wei, GUO Bao-Guo, XU Hai-Yun   

  1. (Department of Chemistry, Key Laboratory of New Organic Materials Synthesis, Shangqiu Normal University, Shangqiu 476000)
  • Received:2009-08-19 Revised:2009-12-31 Published:2010-01-29

A novel sulfur-containing ferrocenyl chiral β-amino alcohol ligand has been successfully synthesized from readily available L-methionine through esterification, condensation, reductive alkylation, and further treatment with RMgX. This novel ligand was characterized by IR, 1H NMR, 13C NMR and HRMS techniques.

Key words: sulfur-containing, β-amino alcohol, L-methionine, asymmetric synthesis