Palladium-catalyzed cross-coupling reaction of phenyl fluoroalkanesulfonates with allyltributyltin

Chin. J. Org. Chem. ›› 1987, Vol. 7 ›› Issue (6): 474-476. Previous Articles Next Articles

钯催化下氟烷基磺酸苯酯与三丁基烯丙基锡的交叉偶合反应

陈庆云;何亚波;杨震宇

中国科学院上海有机化学研究所

发布日期:1987-12-25

Palladium-catalyzed cross-coupling reaction of phenyl fluoroalkanesulfonates with allyltributyltin

CHEN QINGYUN;HE YABO;YANG ZHENYU

Published:1987-12-25

Abstract

Stirring ROSO2R1 [R = Ph, substituted Ph; R1 = CF3, CF2CF2O(CF2CF2)nH; n = 1, 2] with Pd(PPh3)4, LiCl, and Bu3SnCH3CH:CH2 in DMF at 9?gave 43-81% RCH2CH:CH2.

Key words: CATALYSIS, PHENYLESTER, TRIPHENYLPHOSPHINE, COUPLING REACTION, TIN COMPOUND, PALLADIUM COMPLEX, PROPENE P, BUTANE P, FLUOROCARBON, ALKYLSULFONATE

CLC Number:

O627

Cite this article

CHEN QINGYUN;HE YABO;YANG ZHENYU. Palladium-catalyzed cross-coupling reaction of phenyl fluoroalkanesulfonates with allyltributyltin[J]. Chin. J. Org. Chem., 1987, 7(6): 474-476.

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钯催化下氟烷基磺酸苯酯与三丁基烯丙基锡的交叉偶合反应

Palladium-catalyzed cross-coupling reaction of phenyl fluoroalkanesulfonates with allyltributyltin

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