Chin. J. Org. Chem. ›› 1996, Vol. 16 ›› Issue (1): 29-33. Previous Articles     Next Articles

Original Articles

手性恶唑硼烷结构与还原苯基乙基甲酮的对映选择性研究

蒋耀忠;秦勇;宓爱巧;李智;陈新滋;杨登贵   

  1. 中国科学院成都有机化学研究所;中国科学院不对称合成联合开放实验室;香港理工大学应用生物及化学科技学系;台湾中兴大学化学系
  • 发布日期:1996-02-25

The structure of chiral oxazaborolidine and the enantioselective borane reduction of propiophenone

JIANG YAOZHONG;QIN YONG;MI AIQIAO;LI ZHI;CHEN XINZI;YANG DENGGUI   

  • Published:1996-02-25

An effect of substituent of chiral 1,3,2-oxazaborolidine on enantioselectivity was studied by employing propiophenone as reducing substrate. The results indicated that the configuration and enantioselectivity of product were mainly controlled by the substituent at the carbon 4 of oxazaborolidine in CBS reduction.

Key words: CATALYST, GAS CHROMATOGRAPHY, ELEMENTAL ANALYSIS, REDUCTION REACTION, PROTON MAGNETIC RESONANCE SPECTROMETRY

CLC Number: