Recent Progresses in the Epoxidation of Olefins UsingHydrogen Peroxide as Oxidant

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Chin. J. Org. Chem. ›› 2007, Vol. 27 ›› Issue (03): 358-367. Previous Articles Next Articles

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以双氧水为氧源的烯烃环氧化反应

欧阳小月^a，江焕峰*^,b

(^a中国科学技术大学化学系合肥 230026)
(^b华南理工大学化学科学学院广州 510640)

收稿日期:2006-01-26 修回日期:2006-05-23 发布日期:2007-02-13
通讯作者: 江焕峰

Recent Progresses in the Epoxidation of Olefins UsingHydrogen Peroxide as Oxidant

OUYANG Xiao-Yue^a,JIANG Huan-Feng*^,b

(^aDepartment of Chemistry, University of Science and Technology of China, Hefei 230026)
(^bCollege of Chemistry, South China University of Technology, Guangzhou 510640)

Received:2006-01-26 Revised:2006-05-23 Published:2007-02-13

Contact: JIANG Huan-Feng

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Abstract

Based on the reaction medium and the elements in the catalysts, the recent progresses of epoxidation of alkenes with hydrogen peroxide have been reviewed.

Key words: hydrogen peroxide, catalysis, epoxidation, olefin

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OUYANG Xiao-Yue^a,JIANG Huan-Feng*^,b. Recent Progresses in the Epoxidation of Olefins UsingHydrogen Peroxide as Oxidant[J]. Chin. J. Org. Chem., 2007, 27(03): 358-367.

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[1]	Fakai Zou, Nengzhong Wang, Hui Yao, Hui Wang, Mingguo Liu, Nianyu Huang. Regio- and Stereo-selective Synthesis of 1β-/3R-Aryl Thiosugar [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 593-604.
[2]	Jiyu Liu, Shengyu Li, Kuan Chen, Yin Zhu, Yuan Zhang. Triphenylamine-Based Ordered Mesoporous Polymer as a Metal-Free Photocatalyst for Oxidation of Thiols to Disulfide [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 605-612.
[3]	Shuang Yang, Xinqiang Fang. Kinetic Resolutions Enabled by N-Heterocyclic Carbene Catalysis: An Update [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 448-480.
[4]	Luyao Li, Zhongwen He, Zhenguo Zhang, Zhenhua Jia, Teck-Peng Loh. Application of Triaryl Carbenium in Organic Synthesis [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 421-437.
[5]	Wanting Chen, Xiongwei Zhong, Jiale Xing, Changshu Wu, Yang Gao. Progress in Asymmetric Catalytic Synthesis of C—N Axis Chiral Compounds [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 349-377.
[6]	Jing Huang, Yihua Yang, Zhanhui Zhang, Shouxin Liu. Recent Progress on Green Methods and Technologies for Efficient Formation of Amide Bonds [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 409-420.
[7]	Jie Liu, Feng Han, Shuangyan Li, Tianyu Chen, Jianhui Chen, Qing Xu. Transition Metal-Free Selective Aerobic Olefination of Methyl N-Heteroarenes with Alcohols [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 573-583.
[8]	Qinggang Mei, Qinghan Li. Recent Progress of Visible Light-Induced the Synthesis of C(3) (Hetero)arylthio Indole Compounds [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 398-408.
[9]	Yang Li, Yanan Dong, Yuehui Li. Efficient Synthesis of Nitrile Compounds through Amide Conversion via N-Boroamide Intermediates [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 638-643.
[10]	Sida Li, Xin Cui, Xing-Zhong Shu, Lipeng Wu. Titanium-Catalyzed Synthesis of 1,1-Diborylalkanes from Aryl Alkenes [J]. Chinese Journal of Organic Chemistry, 2024, 44(2): 631-637.
[11]	Mengzhu Li, Boying Meng, Wenjie Lan, Bin Fu. Synthesis of 2,3-Disubstituted Dihydrobenzofurans from o-Quinone Methides and Sulfur Ylides [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 195-203.
[12]	Hong'en Tong, Hongyu Guo, Rong Zhou. Progress on Visible-Light Promoted Addition Reactions of Inert C—H Bonds to Carbonyls [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 54-69.
[13]	Xianqiang Meng, Yi Yang, Wanjie Liang, Jingtao Wang, Rongkui Zhang, Hui Liu. Palladium-Catalyzed Regioselective Aryl Phenoxylation of Allenamide [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 224-231.
[14]	Yanshuo Zhu, Hongyan Wang, Penghua Shu, Ke'na Zhang, Qilin Wang. Recent Advances on Alkoxy Radicals-Mediated C(sp³)—H Bond Functionalization via 1,5-Hydrogen Atom Transfer [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 1-17.
[15]	Quanbin Jiang. Progress in Synthesis of Axially Chiral Compounds through aza-Vinylidene o-Quinone Methide Intermediates [J]. Chinese Journal of Organic Chemistry, 2024, 44(1): 159-172.