Chinese Journal of Organic Chemistry ›› 2021, Vol. 41 ›› Issue (8): 3249-3255.DOI: 10.6023/cjoc202103015 Previous Articles Next Articles
ARTICLES
收稿日期:
2021-03-06
修回日期:
2021-04-16
发布日期:
2021-05-08
通讯作者:
林彩霞, 袁耀锋
基金资助:
Lingxiang Lian, Jingyi Yin, Caixia Lin(), Keyin Ye, Yaofeng Yuan()
Received:
2021-03-06
Revised:
2021-04-16
Published:
2021-05-08
Contact:
Caixia Lin, Yaofeng Yuan
Supported by:
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Lingxiang Lian, Jingyi Yin, Caixia Lin, Keyin Ye, Yaofeng Yuan. Phosphine Oxide-Directed Palladium-Catalyzed Heck-Type Functionalization of o-Carboranes[J]. Chinese Journal of Organic Chemistry, 2021, 41(8): 3249-3255.
Entry | Cat. | Ag salt | x | Yieldb/% |
---|---|---|---|---|
1 | Pd(OAc)2 | AgOAc | 2 | <5 |
2 | Pd(TFA)2 | AgOAc | 2 | 13 |
3 | Pd(OAc)2 | AgTFA | 2 | 21 |
4 | Pd(TFA)2 | AgTFA | 2 | 32 |
5 c | Pd(TFA)2 | AgTFA | 3 | 46 |
6c,d | Pd(TFA)2 | AgTFA | 3 | 54 (46) e |
Entry | Cat. | Ag salt | x | Yieldb/% |
---|---|---|---|---|
1 | Pd(OAc)2 | AgOAc | 2 | <5 |
2 | Pd(TFA)2 | AgOAc | 2 | 13 |
3 | Pd(OAc)2 | AgTFA | 2 | 21 |
4 | Pd(TFA)2 | AgTFA | 2 | 32 |
5 c | Pd(TFA)2 | AgTFA | 3 | 46 |
6c,d | Pd(TFA)2 | AgTFA | 3 | 54 (46) e |
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