Application of a Series of Chiral Bidentate Ligands in Asymmetric Oxidation of Sulfide

Chinese Journal of Organic Chemistry ›› 2004, Vol. 24 ›› Issue (5): 558-562. Previous Articles Next Articles

系列手性二齿配体在硫醚的不对称氧化反应中的应用

彭云贵^b, 冯小明^*,a, 崔欣^c, 蒋耀忠^c

^a四川大学化学学院四川省绿色化学与技术重点实验室成都 610064
^b西南师范大学化学化工学院重庆 400715
^c中国科学院成都有机化学研究所不对称合成联合开放实验室成都 610041

收稿日期:2003-07-07 修回日期:2003-10-14 接受日期:2003-11-17 发布日期:2022-09-20
基金资助:
国家自然科学基金(No. 29832020)资助项目.

Application of a Series of Chiral Bidentate Ligands in Asymmetric Oxidation of Sulfide

PENG, Yun-Gui^b, FENG, Xiao-Ming^*,a, CUI, Xin^c, JIANG, Yao-Zhong^c

^aSichuan Key Laboratory of Green Chemistry and Technology, College of Chemistry, Sichuan University, Chengdu 610064
^bSchool of Chemistry and Chemical Engineering, Southwest Normal University, Chongqing 400715
^cUnion Laboratory of Asymmetric Synthesis, Chengdu Institute of OrganicChemistry, Chinese Academy of Sciences, Chengdu 610041

Received:2003-07-07 Revised:2003-10-14 Accepted:2003-11-17 Published:2022-09-20
Contact: *E-mail: xmfeng@scu.edu.cn

Abstract

A series of chiral bidentate ligands were designed and synthesized, and their complexes, which derived from coordinating with Ti(OPr-i)₄, were employed in the catalytic asymmetric oxidation of sulfide. Both the influence of the structure of the chiral ligands to the reactivity and enantioselectivity and the relationship of the configurations between the chiral ligands andthe products were investigated.

Key words: chiral ligand, catalysis, sulfide, asymmetric oxidation

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PENG, Yun-Gui, FENG, Xiao-Ming, CUI, Xin, JIANG, Yao-Zhong. Application of a Series of Chiral Bidentate Ligands in Asymmetric Oxidation of Sulfide[J]. Chinese Journal of Organic Chemistry, 2004, 24(5): 558-562.

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系列手性二齿配体在硫醚的不对称氧化反应中的应用

Application of a Series of Chiral Bidentate Ligands in Asymmetric Oxidation of Sulfide

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