Chinese Journal of Organic Chemistry ›› 2023, Vol. 43 ›› Issue (10): 3508-3525.DOI: 10.6023/cjoc202306019 Previous Articles     Next Articles

Special Issue: 有机硅化学专辑-2023

过渡金属催化硅杂环丁烷的C—Si键断裂反应研究进展

刘敏, 亓丽萍*(), 赵东兵*()   

  1. 南开大学元素有机化学国家重点实验室 天津 300071
  • 收稿日期:2023-06-22 修回日期:2023-08-25 发布日期:2023-08-30
  • 基金资助:
    国家自然科学基金(22022103); 国家自然科学基金(22071114)

Recent Advances in Transition Metal-Catalyzed C—Si Bond Cleavage of Silacyclobutanes

Min Liu, Liping Qi(), Dongbing Zhao()   

  1. State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071
  • Received:2023-06-22 Revised:2023-08-25 Published:2023-08-30
  • Contact: *E-mail: qiliping@nankai.edu.cn; dongbing.chem@nankai.edu.cn
  • Supported by:
    National Natural Science Foundation of China(22022103); National Natural Science Foundation of China(22071114)

Due to the widespread application of various organosilicon compounds in material science, electronic devices and pharmaceutical research, it is of great significance to develop green and efficient synthetic methods for diverse silicon-con- taining molecules. Silacyclobutane is an important kind of small-membered rings, which exhibits unique reactivities under transition metal catalysis to cleave the C—Si bond driven by the inherent ring strain and Lewis acidity. The resulting Si—M species can then be transformed into various organosilicon compounds. Herein, the recent advances of Pd, Rh, and Ni-catalyzed C—Si bond cleavage reactions of silacyclobutanes are summarized in detail, and the mechanism and development tendency of such reactions are briefly discussed.

Key words: transition metal catalysis, silacyclobutane, C—Si bond cleavage