Chinese Journal of Organic Chemistry ›› 2023, Vol. 43 ›› Issue (10): 3454-3469.DOI: 10.6023/cjoc202306028 Previous Articles     Next Articles

Special Issue: 有机硅化学专辑-2023

可见光催化有机硅的合成研究进展

陈凤娟, 刘罗, 张子露*(), 曾伟   

  1. 华南理工大学化学与化工学院 广州 510640
  • 收稿日期:2023-06-30 修回日期:2023-08-31 发布日期:2023-09-08
  • 基金资助:
    国家自然科学基金(22271100)

Recent Progress in Synthesis of Organosilanes Driven by Visible-Light

Fengjuan Chen, Luo Liu, Zilu Zhang(), Wei Zeng   

  1. School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640
  • Received:2023-06-30 Revised:2023-08-31 Published:2023-09-08
  • Contact: *E-mail: zengwei@scut.edu.cn
  • Supported by:
    National Natural Science Foundation of China(22271100)

Silahydrocarbons are often encountered in pharmaceuticals and material chemistry. In comparison with all-carbon parent compounds, carbon/silicon switch generally endows the corresponding compounds with different biological activity and physical-chemical properties. In this review, the methods and strategies of synthesis of organosilanes by photoredox in recent years are reviewed, and the corresponding reaction mechanisms and limitations are discussed.

Key words: photocatalysis, silicon radical, hydrosilylation, silacarboxylation, defluorosilylation