Chinese Journal of Organic Chemistry 2023, 43(3)

- About the Cover:
  
  Photocatalytic heterogeneous chlorotrifluoromethylation and iodoperfluoroalkylation of unactivated terminal alkenes achieved under the catalysis of PTH-POP (phe-nylphenothiazine-based porous organic polymer) are reported by Wang, Gao, Zhou and Zhang on page 1136. This method offers a transition-metal-free and recyclable platform to access valuable perfluoroalkylated compounds in a highly efficient fashion.
- About the Cover:
  
  The catalytic asymmetric reactions involving o-hydroxy- benzyl alcohols, a kind of o-quinone methide precursors with unique advantages, are summarized by Wang, Yang, Zhang and Shi on page 974. This review will open a new window for the design of new kinds of o-hyd- roxybenzyl alcohols and their involved catalytic asym-metric reactions. Notably, this review is dedicated to the special issue “Women Scientists in China” to celebrate the International Women’s Day.
- About the Cover:
  
  A light-promoted radical tandem cyclization reaction to synthesize difluoroalkylindoles was developed by Zhao, Wei, Ke, and Li on page 1102. By using difluorobromo- esters and 3-alkenyl indoles, varies of fluorine-contain- ing polycyclic indoles were generated in an easy-to- operate and mild in conditions with a wide range of substrate adaptability and good yields.
- About the Cover:
  
  The reaction of transition metals catalyzed the activation of C(sp³)—H bonds to form carbon-nitrogen bonds has been a challenging and hot research area. Important progress has been made in directing group-assisted C(sp³)—H bond amination reactions, and many catalyst systems based on different transition metals with cheap and efficient amination reagents have been developed. The research progress of transition metal-catalyzed C(sp³)—H nitrene insertion reaction assisted by dire- cting groups in the past decade is reviewed by Yang, Liu, and Wang on page 914
2023, 43(3)

25 March 2023
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REVIEWS ARTICLES HIGHLIGHTS

REVIEWS

Recent Advances of Efficient Synthesis of Chiral Molecules Promoted by Pd/Chiral Phosphoric Acid Synergistic Catalysis

Xun Xiang, Zhaolin He, Xiuqin Dong

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 791-808 DOI: 10.6023/cjoc202211043

Abstract( 1021) HTML( 73) PDF(1005KB)( 1463 )

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Research Progress of Reaction-Based Probes for Detecting Fluoride Ion

Yanjie Qu, Yajun Li, Hongli Bao

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 809-825 DOI: 10.6023/cjoc202302015

Abstract( 625) HTML( 40) PDF(1644KB)( 1319 )

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Recent Advances in the Synthesis of Fused Heterocyclic Compounds and Their Antitumor Activities

Kanghui Duan, Junlong Tang, Wanqing Wu

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 826-854 DOI: 10.6023/cjoc202211046

Abstract( 894) HTML( 66) PDF(1385KB)( 1442 )

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Z∶E Selective Preparation of Disubstituted Internal Alkenes and Trisubstituted Alkenes

Ping Guo, Yong Zhou, Jie Zhao

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 855-872 DOI: 10.6023/cjoc202212039

Abstract( 1049) HTML( 61) PDF(1184KB)( 1388 )

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Research Progress on Synthesis of Thioflavonoids

Ling Meng, Jun Wang

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 873-891 DOI: 10.6023/cjoc202301004

Abstract( 663) HTML( 58) PDF(1028KB)( 1257 )

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Progress on the Synthesis and Activity of Cyclic Dinucleotides as Stimulator of Interferon Gene (STING) Agonists

Tianyang Wang, Yan-Mei Li

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 892-913 DOI: 10.6023/cjoc202211049

Abstract( 737) HTML( 44) PDF(883KB)( 974 )

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Recent Progress in Transition Metal Catalyzed C(sp³)—H Nitrene Insertion Reactions Assisted by Directing Groups

Xing Yang, Xu Liu, Lijia Wang

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 914-923 DOI: 10.6023/cjoc202211041

Abstract( 658) HTML( 45) PDF(706KB)( 1241 )

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Application of Ligands in Cp*Rh(III)-Catalyzed C—H Bond Functionalization Reaction

Yannian Pan, Xiao Qin, Chengkai Yuan, Yi Lu

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 924-948 DOI: 10.6023/cjoc202211039

Abstract( 742) HTML( 58) PDF(1175KB)( 1143 )

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Research Progress of Lewis Acid and Base Pairs Applied in Materials Chemistry

Lijuan Xiao, Yanping Zhang, Miao Hong

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 949-960 DOI: 10.6023/cjoc202301009

Abstract( 840) HTML( 49) PDF(1007KB)( 1091 )

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Recent Advances on Catalytic Enantioselective Protonation for Construction of α-Tertiary Carbonyl Compounds

Weidi Cao, Xiaohua Liu

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 961-973 DOI: 10.6023/cjoc202211045

Abstract( 909) HTML( 29) PDF(1001KB)( 1234 )

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Advances in Catalytic Asymmetric Reactions Involving o-Hydroxybenzyl Alcohols

Haiqing Wang, Shuang Yang, Yuchen Zhang, Feng Shi

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 974-999 DOI: 10.6023/cjoc202211022

Abstract( 1450) HTML( 76) PDF(1236KB)( 1838 )

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Research Progress in Ortho-C—H Bond Functionalization of Rylene Diimides

Kongchuan Wu, Kaihong Lu, Jianbin Lin, Huijun Zhang

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 1000-1011 DOI: 10.6023/cjoc202211042

Abstract( 739) HTML( 30) PDF(1176KB)( 826 )

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α-Acylation of Olefins via Photocatalysis

Hongyu Hou, Yuanyuan Cheng, Bin Chen, Chenho Tung, Lizhu Wu

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 1012-1022 DOI: 10.6023/cjoc202211048

Abstract( 913) HTML( 36) PDF(787KB)( 1367 )

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Recent Advances in Nickel Catalyzed Asymmetric Acylation Reactions

Yanyan Zhang, Zhuzhu Zhang, Shengqing Zhu, Lingling Chu

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 1023-1035 DOI: 10.6023/cjoc202211032

Abstract( 1459) HTML( 54) PDF(735KB)( 1774 )

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Recent Advances in Ionic Transfer Reactions

Luomo Li, Xiaohui Yang

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 1036-1044 DOI: 10.6023/cjoc202211047

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Recent Advances in Transition Metal-Catalyzed B—H Bond Activation for Synthesis of o-Carborane Derivatives with B—Heteroatom Bond

Hairui Jia, Zaozao Qiu

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 1045-1068 DOI: 10.6023/cjoc202211040

Abstract( 570) HTML( 31) PDF(3417KB)( 895 )

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Recent Advances of the Atherton-Todd Reaction

Siqiang Fang, Zanjiao Liu, Tianli Wang

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 1069-1083 DOI: 10.6023/cjoc202210032

Abstract( 1053) HTML( 48) PDF(873KB)( 2087 )

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ARTICLES

N-Heterocyclic Carbene (NHC)-Catalyzed [4+3] Cycloaddition to Synthesize 4-Aminobenzoheptenolactons

Chunbo Dai, Siqi Xia, Xiaoyu Chen, Limin Yang

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 1084-1090 DOI: 10.6023/cjoc202301011

Abstract( 573) HTML( 35) PDF(1050KB)( 872 )

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Copper-Catalyzed Allylic C(sp³)—H Sulfonylation of Cyclic Olefins

Chunyang Liu, Yan Li, Qian Zhang

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 1091-1101 DOI: 10.6023/cjoc202211028

Abstract( 668) HTML( 42) PDF(587KB)( 795 )

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Visible Light-Catalyzed Synthesis of Difluoroalkylated Polycyclic Indoles

Jinxiao Zhao, Tonghui Wei, Sen Ke, Yi Li

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 1102-1114 DOI: 10.6023/cjoc202212032

Abstract( 478) HTML( 33) PDF(845KB)( 766 )

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Ir(III)-Catalyzed Novel Three-Component Cascade Trifluoroethoxylation and One-Pot Method to Construct Complex Amide Compounds

Chengfu Zeng, Yuan He, Qing Li, Lin Dong

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 1115-1123 DOI: 10.6023/cjoc202210033

Abstract( 384) HTML( 11) PDF(473KB)( 402 )

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Synthesis and Characterization of Zinc, Lithium and Magnesium Complexes Containing Pyrrolyl Ligands, and Utilization as Catalysts in Borylation of Aryl Iodides and Hydroboration of Aldehydes and Ketones

Yan Dang, Chaohong Jia, Yalan Wang, Li Wang, Yafei Li, Yahong Li

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 1124-1135 DOI: 10.6023/cjoc202211038

Abstract( 399) HTML( 19) PDF(1815KB)( 623 )

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Haloperfluoroalkylation of Unactivated Terminal Alkenes over Phenylphenothiazine-Based Porous Organic Polymers

Rui Wang, Lang Gao, Cen Zhou, Xiao Zhang

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 1136-1145 DOI: 10.6023/cjoc202211013

Abstract( 1015) HTML( 48) PDF(1624KB)( 879 )

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Difluorocarbene-Enabled Synthesis of 3-Substituted-2-oxoindoles from o-Vinylanilines

Hua Huang, Xin Li, Jianke Su, Qiuling Song

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 1146-1156 DOI: 10.6023/cjoc202210031

Abstract( 465) HTML( 8) PDF(587KB)( 688 )

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Photocatalyzed 2∶2 Coupling of Styrene and BrCF₂CO₂Me: A Facile Synthesis of Bis-difluoroacetylated Hexestrol Derivatives

Shenhao Chen, Song Zou, Chanjuan Xi

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 1157-1167 DOI: 10.6023/cjoc202210009

Abstract( 594) HTML( 19) PDF(875KB)( 503 )

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High Regioselective Synthesis of N²-Substituted-1,2,3-triazole via N-Sulfonyl-1,2,3-triazole Coupling with Alcohol Catalyzed by in-situ Generated Sulfonic Acid

Jian Ji, Jinhua Liu, Cong Guan, Xuwen Chen, Yun Zhao, Shunying Liu

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 1168-1176 DOI: 10.6023/cjoc202209021

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Green Method for Constructing Phthalides via Oxidative Coupling of Aromatic Acids and Acrylates in Neat Water and Air

Wenting Wei, Zhuangzhuang Li, Wandi Li, Jiaqi Li, Xianying Shi

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 1177-1186 DOI: 10.6023/cjoc202208034

Abstract( 543) HTML( 22) PDF(517KB)( 520 )

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Rhodium-Catalyzed Tandem Acylmethylation/Annulation Reactions of 2-Aryl-2H-indazoles with Sulfoxonium Ylides: Easy Access to 6-Arylindazolo[2,3-a]quinolines

Zhen Tang, Chao Pi, Yangjie Wu, Xiuling Cui

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 1187-1196 DOI: 10.6023/cjoc202206052

Abstract( 569) HTML( 14) PDF(654KB)( 565 )

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HIGHLIGHTS

Selective Formal Carbene Insertion into C—B Bonds of Diboronates

Xin Li, Qiuling Song

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 1197-1198 DOI: 10.6023/cjoc202300011

Abstract( 462) HTML( 24) PDF(376KB)( 641 )

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Alternating Current Promoted Silver Catalysis for C—H Phosphorylation

Na Chen, Haichao Xu

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 1199-1200 DOI: 10.6023/cjoc202300012

Abstract( 283) HTML( 19) PDF(348KB)( 590 )

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Copper-Catalyzed Enantioselective Radical Heteroatomic S—O Cross-Coupling

Yuxuan Han, Xiuling Cui

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 1201-1202 DOI: 10.6023/cjoc202300013

Abstract( 284) HTML( 13) PDF(387KB)( 464 )

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Copper(I)-Catalyzed Asymmetric Conjugate Addition of 1,4-Dienes to β-Substituted Alkenyl Azaarenes

Yanli Yin, Zhiyong Jiang

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 1203-1205 DOI: 10.6023/cjoc202300014

Abstract( 644) HTML( 20) PDF(402KB)( 434 )

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Photoinduced Gold-Catalyzed Divergent Dechloroalkylation of gem-Dichloroalkanes

Peizhuo Lü, Yuanhong Liu

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 1206-1207 DOI: 10.6023/cjoc202300015

Abstract( 341) HTML( 17) PDF(648KB)( 618 )

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Asymmetric Construction of Axially Chiral Arylpyrazole-Based Phosphorus Frameworks by Dipeptide-Phosphonium Salt Catalysis

Ziqi Zhu, Feng Shi

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 1208-1210 DOI: 10.6023/cjoc202300016

Abstract( 324) HTML( 22) PDF(479KB)( 527 )

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Cobalt-Catalyzed Nitrogen Atom Insertion and Ring Expansion of Cycloalkenes

Baoying Zhu, Lingbo Qu, Conghui Tang

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 1211-1212 DOI: 10.6023/cjoc202300017

Abstract( 555) HTML( 27) PDF(355KB)( 678 )

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Nickel-Catalyzed Enantioselective Hydrosilylation of 1,1-Disubstituted Allenes

Shaowei Chen, Xiao Shen

Chinese Journal of Organic Chemistry 2023, 43 (3), pp 1213-1214 DOI: 10.6023/cjoc202300018

Abstract( 562) HTML( 23) PDF(374KB)( 562 )

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