Acta Chimica Sinica ›› 1987, Vol. 45 ›› Issue (5): 521-524. Previous Articles    

Original Articles

烯基Grignard试剂与二苯基卤甲烷的单电子转移反应

党海山;刘有成   

  1. 兰州大学化学系
  • 发布日期:1987-05-15

One-electron transfer reactions of vinylic grignard reagents with diphenylmethyl halides

DANG HAISHAN;LIU YOUCHENG   

  • Published:1987-05-15

Reaction of (Z)-MeCH:CHMgBr with Ph2CHBr in THF gave 20% MeCH:CH2, 41% Ph2CHCHPh2, 6% Ph2CH2, 22% MeCH:CHCH:CHMe, and 12% (Z)- and (E)-Ph2CHCH:CHMe.

Key words: REACTION MECHANISM, BROMOHYDROCARBON, ELECTRON TRANSFER, STEREOCHEMISTRY, DIPHENYLMETHANE P, PROPENE P, MAGNESIUM COMPOUNDS, GRIGNARD REAGENT, SINGLE ELECTRON TRANSFER REACTION

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