有机化学 ›› 2016, Vol. 36 ›› Issue (4): 782-786.DOI: 10.6023/cjoc201511009 上一篇    下一篇

研究论文

基于吖啶的手性荧光传感器的合成及其对酒石酸识别性能研究

宋盼a, 王超玉a, 王鹏a, 刘晓燕a, 徐括喜a,b   

  1. a. 河南大学精细化工研究所 开封 475004;
    b. 河南大学环境与分析科学研究所 开封 475004
  • 收稿日期:2015-11-04 修回日期:2015-12-04 发布日期:2015-12-21
  • 通讯作者: 徐括喜 E-mail:xukx@henu.edu.cn
  • 基金资助:

    国家自然科学基金(No.U1404207)和河南省科技创新团队(No.15IRTSTHN005)资助项目.

Synthesis and Chiral Detecting of Tartrate Fluorescence Sensors Based on Acridine

Song Pana, Wang Chaoyua, Wang Penga, Liu Xiaoyana, Xu Kuoxia,b   

  1. a. Institute of Fine Chemical and Engineering, Henan University, Kaifeng 475004;
    b. Institute of Environmental and Analytical Sciences, Henan University, Kaifeng 475004
  • Received:2015-11-04 Revised:2015-12-04 Published:2015-12-21
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. U1404207) and the He'nan Innovative Research Team in University (No. 15IRTSTHN005).

以吖啶和α-羟基羧酸为原料合成了三个手性荧光化学传感器L-1,D-1L-2,其结构经红外、核磁、质谱表征.通过紫外光谱、荧光光谱滴定等实验的方法研究了对手性羧酸阴离子的识别能力.研究结果表明L-1D-1具有对酒石酸阴离子良好的对映选择性识别性能,且主客体间形成了1∶1的络合物.

关键词: 吖啶, 手性, 荧光, 化学传感器, 酒石酸

Three chiral fluorescence chemosensors L-1, D-1 and L-2 based on acridine were synthesized. The structures of these compounds were characterized by IR, NMR and MS. The chiral recognition property of such sensors was studied by UV-vis and fluorescence titration. The results demonstrate that the sensors L-1 and D-1 exhibit a good enantioselectivity recognition ability toward tartrate and formed 1∶1 complex.

Key words: acridine, chiral, fluorescence, chemosensor, tartrate