有机化学 ›› 2017, Vol. 37 ›› Issue (9): 2211-2220.DOI: 10.6023/cjoc201703038 上一篇    下一篇

综述与进展

C-S键构筑的研究进展

孙丰莉a, 刘学民a, 陈新志b, 钱超b, 葛新a,b   

  1. a 江南大学化学与材料工程学院 无锡 214122;
    b 浙江大学生物质化工教育部重点实验室 杭州 310027
  • 收稿日期:2017-03-22 修回日期:2017-05-07 出版日期:2017-09-25 发布日期:2017-05-25
  • 通讯作者: 葛新 E-mail:gexin@jiangnan.edu.cn
  • 基金资助:

    国家自然科学基金(Nos.21476194,21606104)、中国博士后科学基金(No.2016M590536)和江南大学自主科研计划(No.JUSRP115A05)资助项目.

Progress in the Formation of C-S Bond

Sun Fenglia, Liu Xuemina, Chen Xinzhib, Qian Chaob, Ge Xina,b   

  1. a School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122;
    b Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Zhejiang University, Hangzhou 310027
  • Received:2017-03-22 Revised:2017-05-07 Online:2017-09-25 Published:2017-05-25
  • Contact: 10.6023/cjoc201703038 E-mail:gexin@jiangnan.edu.cn
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21476194, 21606104), the Project Funded by China Postdoctoral Science Foundation (No. 2016M590536) and the Fundamental Research Funds for the Central Universities (No. JUSRP115A05).

C-S键的构筑是有机合成的基础,对于天然产物、重要生物分子的合成和功能性材料的开发等具有重要作用,因此受到了广泛的关注.对近年来C-S键的构筑方面取得的进展进行了归纳,根据C-S键的成键方式不同,分别从C-H键活化、脱羧偶联反应、Ullmann反应这三个方面进行了总结,并从配体类型对Ullmann C-S成键展开论述.

关键词: Ullmann反应, C-S键, 偶联反应

The construction of C-S bond is the fundamental of organic synthesis, which plays an important role in the synthesis of natural products, biomolecules and functional materials. Thus, it has been received much attention. Base on the different C-S bonding method, the C-H bond activation, decarboxylation coupling reaction and Ullmann reaction are introduced. The ligands of Ullmann C-S coupling are also summarized.

Key words: Ullmann reaction, C-S bond, coupling reaction