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有机化学
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有机化学 ›› 2011, Vol. 31 ›› Issue (06): 775-783.    下一篇

综述与进展

傅-克酰基化反应的机理及动力学研究进展

黄志良1,2，靳立群2，雷爱文*,2   

  1. (1华中农业大学理学院应用化学系 武汉 430070)
    (2武汉大学化学与分子科学学院 武汉 430072)
  • 收稿日期:2010-09-19 修回日期:2010-11-30 发布日期:2010-12-16
  • 通讯作者: 雷爱文 E-mail:aiwenlei@whu.edu.cn

Development of Mechanism Studies and Kinetic Investigations in Friedel-Crafts Acylation

Huang Zhiliang1,2 Jin Liqun2 Lei Ai-wen*,2   

  1. (1 Chemistry Department, College of Science, Huazhong Agriculture University, Wu-han 430070)
    (2 College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072)
  • Received:2010-09-19 Revised:2010-11-30 Published:2010-12-16
  • Contact: Ai-Wen Lei E-mail:aiwenlei@whu.edu.cn

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总结了傅-克酰基化反应提出以来, 化学工作者对该反应的机理方面的研究, 包括动力学研究、中间体结构和性质的. 提出傅-克反应机理目前存在的疑问及机理动力学的发展方向.

关键词: 傅-克酰基化反应, 动力学, 中间体, 反应机理

For the Friedel-Crafts acylation, the kinetic studies, the structure discussion and properties of the intermediate have been summerized. Basing on these studies, the possible mechanisms have been proposed and explained. According to the foregone results, a lot of indistinct doubts remain exist and the direction for the development of the kinetic and mechanism is put forward.

Key words: Friedel-Crafts acylation, kinetic, intermediate, mechanism