有机化学 ›› 2013, Vol. 33 ›› Issue (10): 2119-2130.DOI: 10.6023/cjoc201303040 上一篇    下一篇

综述与进展

二芳基碘鎓盐在有机反应中的研究新进展

肖志超a,b, 夏成峰a   

  1. a 中国科学院昆明植物研究所 植物化学与西部植物资源持续利用国家重点实验室 昆明 650201;
    b 中国科学院大学 北京 100039
  • 收稿日期:2013-03-26 修回日期:2013-04-28 出版日期:2013-10-25 发布日期:2013-05-09
  • 通讯作者: 夏成峰 E-mail:xiachengfeng@mail.kib.ac.cn
  • 基金资助:

    国家自然科学基金(No. 21072201)和国家重点基础研究发展计划(973计划, No. 2011CB915500)资助项目

Progresses of Diaryliodonium Salts in Organic Reactions

Xiao Zhichaoa,b, Xia Chengfenga   

  1. a State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming 650201;
    b University of Chinese Academy of Sciences, Beijing 100039
  • Received:2013-03-26 Revised:2013-04-28 Online:2013-10-25 Published:2013-05-09
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21072201) and the National Basic Research Program of China (973 Program, No. 2011CB915500).

二芳基碘鎓盐作为一种温和、无毒且性质稳定的芳基化试剂, 近年来在有机反应中得到广泛的应用. 综述了它的结构和活性特点、制备方法、参与的C—H芳基化反应、羰基化合物的芳基化反应、串联环化反应以及对杂原子亲核试剂的芳基化反应的研究进展, 并阐述了各类反应的特点、机理和应用.

关键词: 二芳基碘鎓盐, 芳基化, 偶联反应

Diaryliodonium salts, a kind of mild, non-toxic and stable arylation reagent, have wide applications in organic chemistry. This review presents its structure and reaction activity characteristics, preparation methods, recent progresses in arylation of C—H bond, arylation of carbonyl compounds, cascade reaction, as well as arylation of hetero-atom nucleophiles. The characteristics of the reaction mechanisms and their applications are also discussed.

Key words: diaryliodonium salt, arylation, cross-coupling reaction