Chin. J. Org. Chem. ›› 2015, Vol. 35 ›› Issue (8): 1746-1753.DOI: 10.6023/cjoc201502031 Previous Articles     Next Articles



邱淑海a,b, 许胜杰b, 周国富a, 水玲玲a, 朱晓张b   

  1. a 华南师范大学华 南先进光电子研究院彩色电子纸显示技术研究所 广州 510006;
    b 中国科学院化学研究所有机固体院重点实验室 北京 100190
  • 收稿日期:2015-02-26 修回日期:2015-03-30 发布日期:2015-04-03
  • 通讯作者: 水玲玲, 朱晓张;
  • 基金资助:

    国家自然科学基金(Nos. 91333113, 21303060)、国家重点基础研究发展计划(973计划, No. 2014CB643502)、中国科学院先导B专项(No. XDB12010200)、广东省自然科学基金(No. S2013010014418)资助项目.

Synthesis of 1,2,3,4,5-Pentaarylcyclopenta-2,4-diene Derivatives and Their Aggregation-Induced Emission Properties

Qiu Shuhaia,b, Xu Shengjieb, Zhou Guofua, Shui Linglinga, Zhu Xiaozhangb   

  1. a Electronic Paper Display Institute, South China Academy of Advanced Optoelectronics, South China Normal University, Guangzhou 510006;
    b CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190
  • Received:2015-02-26 Revised:2015-03-30 Published:2015-04-03
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 91333113, 21303060), the National Basic Research Program of China (973 Program, No. 2014CB643502), the Strategic Priority Research Program of the Chinese Academy of Sciences (No. XDB12010200), and the Guangdong Natural Science Foundation (No. S2013010014418).

Pentaarylated cyclopentcyclodienes have aggregation-induced emission (AIE) characteristics and can be easily derivatized, but are rarely studied. In order to examine the effect of the electronic properties and the position of the substituents on AIE properties, an expedient method for the synthesis of a series of pentaarylated cyclopentadiene derivatives was developed, and their UV-Vis, fluorescence spectra, fluorescence quantum yields as well as the XRD structures of single crystals were investigated. The AIE properties of pentaarylated cyclopentadiene derivatives were studied in detail.

Key words: pentaarylated cyclopentadienes, aggregation-induced emission