Chin. J. Org. Chem. ›› 2016, Vol. 36 ›› Issue (8): 1824-1838.DOI: 10.6023/cjoc201603014 Previous Articles     Next Articles


Triphos配体在羧酸及其衍生物和CO2的氢化反应中的应用研究进展 2017-2018 Awarded

张琳莉a,b, 韩召斌b, 张磊b, 李明星a, 丁奎岭a,b   

  1. a 上海大学理学院化学系 上海 200436;
    b 中国科学院上海有机化学研究所 金属有机化学国家重点实验室 上海 200032
  • 收稿日期:2016-03-08 修回日期:2016-04-02 发布日期:2016-04-07
  • 通讯作者: 丁奎岭
  • 基金资助:

    国家自然科学基金(Nos. 21472215,21572254)资助项目.

Advances in Hydrogenation of Carboxylic Acid Derivatives and CO2 Using Triphos as the Coordination Ligand

Zhang Linlia,b, Han Zhaobinb, Zhang Leib, Li Mingxinga, Ding Kuilinga,b   

  1. a Department of Chemistry, College of Sciences, Shanghai University, Shanghai 200436;
    b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032
  • Received:2016-03-08 Revised:2016-04-02 Published:2016-04-07
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21472215, 21572254).

The reduction of carbon dioxide, carboxylic acids and their derivatives is one of the fundamental transformations both in academia and industry. Considering the increasing environmental issues, the use of molecular hydrogen as the reducing agent is especially attractive. Due to the mild reaction condition, high reactivity and easy modification of homogeneous catalysis, the development of highly efficient and selective homogeneous hydrogenation catalysts to achieve the goal is becoming a hot topic. Impressive progresses have been made using homogenous catalysts derived from transition metals and various ligands as catalysts. Among them, the catalytic system combined with a transition metal and CH3C(CH2PPh2)3 (triphos) usually shows unique reactivity and selectivity. This review will summarize the advance in the hydrogenation of carbon dioxide, carboxylic acids and their derivatives using Ru/triphos, Co/triphos and Cu/triphos as catalysts, as well as their reaction mechanisms.

Key words: carboxylic acid and derivatives, carbon dioxide, triphos ligand, transition metal, hydrogenation, alcohol, amine