Chin. J. Org. Chem. ›› 2016, Vol. 36 ›› Issue (9): 2130-2135.DOI: 10.6023/cjoc201604039 Previous Articles     Next Articles



苏戈, 吴斗峰, 李巧伟, 侯军利   

  1. 复旦大学化学系 上海 200433
  • 收稿日期:2016-04-19 修回日期:2016-05-13 发布日期:2016-05-19
  • 通讯作者: 侯军利
  • 基金资助:


Synthesis of the Bi-functionalized Pillar[5]arene

Su Ge, Wu Doufeng, Li Qiaowei, Hou Junli   

  1. a Department of Chemistry, Fudan University, Shanghai 200433
  • Received:2016-04-19 Revised:2016-05-13 Published:2016-05-19
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos.21422202, 21572035).

The method for the synthesis of bi-functionalized pillar[5]arenes with amino and ester groups or amino and carboxylic group has been developed. The conformation of the functional group of the pillar[5]arene was investigated by using 1H NMR and X-Ray experiments. The intramolecular hydrogen bonding induces the side-chain of the pillar[5]arene to introvert. And thus, the amino group points to the inside cavity of the pillar[5]arene backbone. The position of the amino group is adjustable by using alkyl chains with different length.

Key words: pillar[5]arene, bi-functionalize, synthesis, conformation analysis