Chin. J. Org. Chem. ›› 2016, Vol. 36 ›› Issue (10): 2353-2367.DOI: 10.6023/cjoc201604053 Previous Articles     Next Articles



徐慧婷a, 张超怀b, 陈钢b, 沈润溥a, 应安国b   

  1. a 绍兴文理学院化学化工学院 绍兴 312000;
    b 台州学院医药化工学院 台州 318000
  • 收稿日期:2016-04-26 修回日期:2016-05-28 发布日期:2016-06-08
  • 通讯作者: 沈润溥,;应安国,;
  • 基金资助:


Application of Task-Specific Ionic liquids to Organic Synthesis

Xu Huitinga, Zhang Chaohuaib, Chen Gangb, Shen Runpua, Ying Anguob   

  1. a School of Chemistry and Chemical Engineering, Shaoxing University, Shaoxing 312000;
    b School of Pharmaceutical and Chemical Engineering, Taizhou University, Taizhou 318000
  • Received:2016-04-26 Revised:2016-05-28 Published:2016-06-08
  • Supported by:

    Project supported by the Natural Science Foundation of Zhejiang Province (No.LY15B060002), the National Natural Science Foundation of China (Nos.21576176, 21106090), and the Science and Technology Innovation Undergraduate Program of Zhejiang Province (No.2015R430015).

Ionic liquids (ILs) have been widely used as green reaction solvents and/or catalysts in organic synthesis due to their advantages, including low volatility, good thermal stability, good solubility and recyclability. ILs have played a significant role in accelerating reaction rate and selectivity. The recent advances in the application of ILs as catalysts or solvents are summarized in this review, such as in Baylis-Hillman reaction, Michael addition, oxidation and reduction reaction, Knoevenagel condensation, aldol reaction, Diels-Alder reaction, Heck coupling reaction, Suzuki reaction, asymmetric reaction, Biginelli reaction, Mannich reaction and Hantzsch reaction. Relationship between structure and catalytic efficiency of ILs as well as plausible mechanism has been discussed, which is beneficial to develop the novel task-specific ionic liquids with diverse functionalities.

Key words: task-specific ionic liquids, organic synthesis, relationship between structure and activity, green chemistry, recy-clability