Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (7): 1626-1637.DOI: 10.6023/cjoc201801046 Previous Articles     Next Articles

Special Issue: 二氧化碳合辑



徐佩, 汪顺义, 方毅, 纪顺俊   

  1. 苏州大学材料与化学化工学部和苏州纳米科技协同创新中心 江苏省有机合成重点实验室 苏州 215123
  • 收稿日期:2018-01-30 修回日期:2018-03-02 发布日期:2018-03-16
  • 通讯作者: 纪顺俊
  • 基金资助:


Research Progress on the Reaction of Carbon Dioxide with Nucleophiles

Xu Pei, Wang Shun-Yi, Fang Yi, Ji Shun-Jun   

  1. Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou 215123
  • Received:2018-01-30 Revised:2018-03-02 Published:2018-03-16
  • Contact: 10.6023/cjoc201801046
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21542015, 21672157), and the Major Basic Research Project of the Natural Science Foundation of the Jiangsu Higher Education Institutions (No. 16KJA150002).

Carbon dioxide as a green and cheap C1 synthon has significant research value and industrial application prospect. In recent years, using carbon dioxide to synthesize cyclic carbamates, quinazoline-2,4-(1H,3H)-diones, cyclic lactones and other heterocyclic compounds have been research hotspot. Many of the heterocyclic compounds can be synthesized by reacting the carbon atom in carbon dioxide with electron deficient with nucleophiles. This review focuses on the recent intermolecular and intramolecular reactions of carbon dioxide with nucleophiles centered around nitrogen, oxygen, or carbon.

Key words: carbon dioxide, nucleophiles, electrophiles, amino, hydroxyl, carbanion