Recent Advances in Asymmetric Hydroformylation

doi:10.6023/cjoc201903044

Chin. J. Org. Chem. ›› 2019, Vol. 39 ›› Issue (6): 1568-1582.DOI: 10.6023/cjoc201903044 Previous Articles Next Articles

Special Issue: 金属有机化学

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不对称氢甲酰化反应研究进展

李帅龙^a, 李庄星^a, 由才^a, 吕辉^a,b,d, 张绪穆^c

a 武汉大学化学与分子科学学院生物医用高分子材料教育部重点实验室武汉 430072;
b 武汉大学化学与分子科学学院有机硅化合物及材料教育部工程中心武汉 430072;
c 南方科技大学化学系深圳格拉布斯研究院深圳 518055;
d 武汉大学索维奇分子科学研究中心武汉 430072

收稿日期:2019-03-22 修回日期:2019-04-23 发布日期:2019-05-06
通讯作者: 吕辉 E-mail:huilv@whu.edu.cn
基金资助:
国家自然科学基金（No.21871212）和湖北省自然科学基金（No.2018CFB430）资助项目.

Recent Advances in Asymmetric Hydroformylation

Li Shuailong^a, Li Zhuangxing^a, You Cai^a, Lü Hui^a,b,d, Zhang Xumu^c

a Key Laboratory of Biomedical Polymers of Ministry of Education, College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072;
b Engineering Research Center of Organosilicon Compounds & Materials, Ministry of Education, College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072;
c Department of Chemistry, Southern University of Science and Technology, Shenzhen Grubbs Institute, Shenzhen 518055;
d Sauvage Center for Molecular Sciences, Wuhan University, Wuhan 430072

Received:2019-03-22 Revised:2019-04-23 Published:2019-05-06
Contact: 10.6023/cjoc201903044 E-mail:huilv@whu.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21871212) and the Natural Science Foundation of Hubei Province (No. 2018CFB430).

Asymmetric hydroformylation is one of the most important reactions for preparation of chiral aldehydes from alkenes. Recently, significant progress has been made in this field and a series of new ligands have been developed. Asymmetric hydroformylation of several important alkenes has been achieved, offering efficient and concise methods for the synthesis of chiral aldehydes. In this review, the achievements of asymmetric hydroformylation of typical alkenes and the development of ligands for asymmetric hydroformylation are summarized.

Key words: alkene, asymmetric hydroformylation, aldehyde, chiral phosphine ligand, rhodium

Cite this article

Li Shuailong, Li Zhuangxing, You Cai, Lü Hui, Zhang Xumu. Recent Advances in Asymmetric Hydroformylation[J]. Chin. J. Org. Chem., 2019, 39(6): 1568-1582.

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不对称氢甲酰化反应研究进展

Recent Advances in Asymmetric Hydroformylation

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