Chin. J. Org. Chem. ›› 2019, Vol. 39 ›› Issue (8): 2251-2256.DOI: 10.6023/cjoc201904017 Previous Articles     Next Articles

Special Issue: 陈茹玉先生诞辰100周年 元素有机化学合辑2018-2019



谷迎春a,b, 黄有a   

  1. a 南开大学化学学院元素有机化学研究所 元素有机化学国家重点实验室 天津 300071;
    b 天津城建大学理学院 天津 300384
  • 收稿日期:2019-04-08 修回日期:2019-05-04 发布日期:2019-05-15
  • 通讯作者: 黄有
  • 基金资助:


Tributylphosphine Catalyzed Cross Rauhut-Currier Reaction of Chalcones and Acrylates

Gu Yingchuna,b, Huang Youa   

  1. a State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071;
    b School of Science, Tianjin Chengjian University, Tianjin 300384
  • Received:2019-04-08 Revised:2019-05-04 Published:2019-05-15
  • Contact: 10.6023/cjoc201904017
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21672109, 21871148, 21472097) and the Natural Science Foundation of Tianjin City (No. 15JCYBJC20000).

Rauhut-Currier (RC) reaction is an effective atom-economic method to construct C-C bond. However, the application of this reaction is limited by the lack of selectivity. Herein, an efficient intermolecular cross Rauhut-Currier reaction between chalcones and acrylates in the presence of the tributylphosphine catalyst was developed, the reactions were carried out in mild conditions, and performed well with a series of substrates, delivering the desired products with acceptable to good yields.

Key words: tributylphosphine, catalysis, Rauhut-Currier reaction, chalcone, acrylate