Chin. J. Org. Chem. ›› 2010, Vol. 30 ›› Issue (07): 981-987. Previous Articles     Next Articles

Reviews

碱性离子液体在有机合成中的应用研究进展

钟涛12,乐长高*1,谢宗波1,曹霞1,吕雪霞1   

  1. (1东华理工大学化学生物与材料科学学院 抚州 344000)
    (2武警黄金第一支队 牡丹江 157021)
  • 收稿日期:2009-06-17 修回日期:2009-09-01 发布日期:2009-12-30
  • 通讯作者: 钟涛 E-mail:zt20311@163.com
  • 基金资助:

    国家自然科学基金(No. 20862001)、教育部新世纪优秀人才支持计划(No. NCET-08-0701)、江西省自然科学基金(No. 2008GZH0055).

Progress in the Application of Basic Ionic Liquids to Organic Synthesis

Zhong Tao12 Le Zhangao*1 Xie Zongbo1 Cao Xia1 Lü Xuexia1   

  1. (1Faculty of Chemistry Biology and Material Science, East China Institute of Technology, Fuzhou 344000) (2Gold Geological Detachment No.1 of Chinese People s Armed Police Force, Mudanjiang 157021)
  • Received:2009-06-17 Revised:2009-09-01 Published:2009-12-30
  • Contact: ZHONG Tao E-mail:zt20311@163.com

The classification and properties of basic ionic liquids are summarized. The advanced progress in the application of basic ionic liquids as reaction medium as well as catalyst to organic synthesis is reviewed, mainly including Michael addition, Mannich reaction, Knoevenagel condensation, Markovnikov addition, Henry reaction, Perkin reaction, Heck coupling reaction, alkylation, carbonylation and interrupted Feist-Benary reaction.

Key words: basic ionic liquid, catalysis, organic synthesis, application