Allylic geminal diacetates as a^1, a^3 synthon A convenient synthesis of bicyclo (3.3.1) nonan-9-one derivatives and its mechanism

Acta Chimica Sinica ›› 1988, Vol. 46 ›› Issue (9): 908-912. Previous Articles Next Articles

Original Articles

烯丙基-1,1-偕二醇二醋酸酯作为a^1, a^3合成子的研究: 合成双环[3.3.1]壬烷-9-酮衍生物的简便方法及其反应机理

黄煜津;陆熙炎

中国科学院上海有机化学研究所

发布日期:1988-09-15

Allylic geminal diacetates as a^1, a^3 synthon A convenient synthesis of bicyclo (3.3.1) nonan-9-one derivatives and its mechanism

HUANG YUJIN;LU XIYAN

Published:1988-09-15

Abstract

2-Acetoxybicyclo[3.3.1]nonan-9-one derivatives I (R, R1 = H, H; Me, H; H, Me) could be synthesized from the reaction of RCH:CR1CH(OAc)2 with pyrrolidine enamine of cyclohexanone under the catalysis of palladium complex in one step. The possible mechanism of this novel reaction is discussed.

Key words: ACETIC ACID ESTER, REACTION MECHANISM, BICYCLIC, TETRAHYDRO-COMPOUNDS, PYRROLE P, PALLADIUM COMPLEX, ALLYL GROUP, CYCLOHEXENE P, KETONE P, NONANE P

CLC Number:

O621

Cite this article

HUANG YUJIN;LU XIYAN. Allylic geminal diacetates as a^1, a^3 synthon A convenient synthesis of bicyclo (3.3.1) nonan-9-one derivatives and its mechanism[J]. Acta Chimica Sinica, 1988, 46(9): 908-912.

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烯丙基-1,1-偕二醇二醋酸酯作为a^1, a^3合成子的研究: 合成双环[3.3.1]壬烷-9-酮衍生物的简便方法及其反应机理

Allylic geminal diacetates as a^1, a^3 synthon A convenient synthesis of bicyclo (3.3.1) nonan-9-one derivatives and its mechanism

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