有机化学 ›› 2012, Vol. 32 ›› Issue (06): 1010-1023.DOI: 10.6023/cjoc1110183 上一篇    下一篇

综述与进展

氮杂富勒烯的合成及反应研究进展

张改红   

  1. 郑州轻工业学院食品与生物工程学院 郑州 450002
  • 收稿日期:2011-10-18 修回日期:2011-12-14 发布日期:2012-01-10
  • 通讯作者: 张改红 E-mail:zhanggaihong@gmail.com
  • 基金资助:
    郑州轻工业学院博士基金(No. 2010BSJJ018)资助项目.

Progress in the Synthesis and Reaction of Azafullerene

Zhang Gaihong   

  1. School of Food and Bioengineering, Zhengzhou University of Light Industry, Zhengzhou 450002
  • Received:2011-10-18 Revised:2011-12-14 Published:2012-01-10
  • Supported by:
    Project supported by the Doctoral Fund Project of Zhengzhou University of Light Industry (No. 2010BSJJ018).

氮杂富勒烯是富勒烯家族中一类非常重要的化合物, 由于其独特的结构和反应活性, 近年来引起了人们的广泛关注. 因此, 对氮杂富勒烯的合成、反应方面的研究进行了概括和总结. 氮杂富勒烯的合成主要有3 种方法(Wudl,Hirsch, Gan), 氮杂富勒烯的反应主要包括自由基反应和亲电芳环取代反应.

关键词: 富勒烯, 碳碳键断裂, 自由基

Azafullerene is a very important compound in fullerene family, which has been attracted extensive attention recently because of its unique structure and reactive activities. Recent progress in the preparation and reaction of azafullerene is summarized in this paper. There are three main methods for the synthesis of azafullerene (Wudl’s method, Hirsch’s method and Gan’s method). Azafullerene reactions include free radical reactions and electrophilic aromatic substitution reaction.

Key words: fullerene, carbon-carbon bond cleavage, free radical