有机化学 ›› 2017, Vol. 37 ›› Issue (10): 2512-2525.DOI: 10.6023/cjoc201604029 上一篇    下一篇

综述与进展

过渡金属催化二环烯烃加成反应的研究进展

杨新, 杨文, 邓颖颍, 杨定乔   

  1. 华南师范大学化学与环境学院 教育部环境理论化学重点实验室 广州 510006
  • 收稿日期:2017-04-18 修回日期:2017-05-22 发布日期:2017-06-23
  • 通讯作者: 杨定乔 E-mail:yangdq@scnu.edu.cn
  • 基金资助:

    国家自然科学基金(Nos.21172081,21372090)、广东省自然科学基金(No.S2013020013091)和广州市科技计划(No.201510010054)资助项目.

Progress in Transition-Metal Catalyzed Bicyclic Olefins Addition Reaction

Yang Xin, Yang Wen, Deng Yingying, Yang Dingqiao   

  1. Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, School of Chemistry and Environment, South China Normal University, Guangzhou 510006
  • Received:2017-04-18 Revised:2017-05-22 Published:2017-06-23
  • Contact: 10.6023/cjoc201604029 E-mail:yangdq@scnu.edu.cn
  • Supported by:

    Project Supported by the National Natural Science Foundation of China (Nos.21172081,21372090),the Natural Science Foundation of Guangdong Province (No.S2013020013091) and the City of Guangzhou Science and Technology Plan Projects (No.201510010054).

综述了近年来过渡金属催化二环烯烃加成反应的研究进展,主要包括了钌、铑、铱、钯、铜、钴、镍和铁催化二环烯烃的加成反应,并对部分加成反应可能的机理进行了讨论.

关键词: 过渡金属, 二环烯烃, 加成反应, 研究进展

In this paper, the recent research progress in transition-metal catalyzed bicyclic olefin addition reactions is reviewed, mainly including Ru, Rh, Ir, Pd, Cu, Co, Ni and Fe etc. Moreover, the possible mechanisms of some parts of addition reactions are also discussed.

Key words: transition-metal, bicyclic olefins, addition reaction, research progress