有机化学 ›› 2020, Vol. 40 ›› Issue (9): 2607-2625.DOI: 10.6023/cjoc202004042 上一篇    下一篇

综述与进展

AlCl3促进的有机反应研究进展

袁康宁a, 赵玉英b, 常宏宏a, 田俊a, 高文超a   

  1. a 太原理工大学生物医学工程学院 太原 030024;
    b 太原科技大学化学与生物工程学院 太原 030021
  • 收稿日期:2020-04-26 修回日期:2020-05-16 发布日期:2020-06-01
  • 通讯作者: 高文超 E-mail:gaowenchao@tyut.edu.cn
  • 基金资助:
    国家自然科学基金(No.21901179)、山西省重点研发计划(国际合作)(No.201803D421093)、山西省自然科学基金(No.201901D211052)以及山西省留学回国人员科研教研(Nos.HGKY2019029,2020-053)资助项目.

Recent Advances in AlCl3-Promoted Organic Reactions

Yuan Kangninga, Zhao Yuyingb, Chang Honghonga, Tian Juna, Gao Wenchaoa   

  1. a College of Biomedical Engineering, Taiyuan University of Technology, Taiyuan 030024;
    b School of Chemical and Biological Engineering, Taiyuan University of Science and Technology, Taiyuan 030021
  • Received:2020-04-26 Revised:2020-05-16 Published:2020-06-01
  • Supported by:
    Project supported by the National Natural Science Foundation of China (No. 21901179), the Key Research and Development Program of Shanxi Province (International Cooperation) (No. 201803D421093), the Natural Science Foundation of Shanxi Province (No. 201901D211052) and the Research Project Supported by Shanxi Scholarship Council of China (Nos. HGKY2019029, 2020-053).

三氯化铝(AlCl3)作为硬路易斯酸的典型代表,其促进的有机转化近些年来越来越受到人们的关注.总结了近10年来通过三氯化铝对含卤素、氧、氮、硫原子化合物及π键的活化完成的多种有机转化,并对所涉及的相关反应及活化机制进行了系统介绍,同时对三氯化铝新的应用领域进行了展望.

关键词: 三氯化铝, 活化作用, 活化机制, 有机催化

As a representative hard Lewis acid, aluminum trichloride (AlCl3) has attracted more and more attention in the past decades. The reactions promoted via the activation of halogens, oxygen, nitrogen, sulfur compounds and π-bonds with AlCl3 are systematically reviewed, and some recent progress in last ten years is updated as well. Moreover, the new application fields of AlCl3 are prospected.

Key words: aluminum trichloride, activation, activation mechanism, organic catalysis