过渡金属催化C—H键硅基化反应构建硅杂环研究进展

doi:10.6023/cjoc202406022

摘要/Abstract

硅杂环是含硅功能分子中非常重要的结构单元, 在合成化学、药物化学和材料化学等领域具有广泛应用, 发展结构多样化硅杂环的高效合成新方法对推动其应用研究具有重要意义. 其中, 过渡金属催化C—H键直接硅基化具有高的原子经济性和步骤经济性特点, 目前已成为构建结构复杂的硅杂环化合物的一种重要方法. 本文总结了近年来过渡金属催化C(sp²)—H键和C(sp³)—H键硅基化反应构筑硅杂环的研究进展.

关键词: 硅杂环, 过渡金属, C—H键活化, 硅基化, 有机硅化合物

Silacycles are essential structural motifs in silicon-containing functional molecules, which are widely used in the fields of synthetic chemistry, pharmaceutical and material science. As such, the development of efficient synthetic methods for these structurally diverse scaffolds is of great significance. Among these, due to its high atomic economy and step economy properties, transition-metal-catalyzed direct C—H silylation provides a powerful and straightforward synthetic method to form diverse silacycles. In this review, the recent progress in the construction of silacycles by transition-metal-catalyzed C(sp²)—H and C(sp³)—H silylation reactions is summarized.

Key words: silacycles, transition-metal, C—H activation, silylation, organosilicon compounds

引用此文

刘泽水, 郭桢桢, 牛俊龙. 过渡金属催化C—H键硅基化反应构建硅杂环研究进展[J]. 有机化学, doi: 10.6023/cjoc202406022.

Ze-Shui Liu, Zhen-Zhen Guo, Jun-Long Niu. Recent Progress in the Construction of Silacycles by Transition-Metal-Catalyzed C—H Silylation[J]. Chinese Journal of Organic Chemistry, doi: 10.6023/cjoc202406022.

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