有机化学 ›› 1986, Vol. 6 ›› Issue (6): 456-459. 上一篇    下一篇

研究论文

卡宾活性中间体在有机合成中的应用II.马鞭草烯醇类似物的合成

吴家骏;陶凤岗;肖守军;吴世辉   

  1. 复旦大学化学系
  • 发布日期:1986-12-25

Application of carbene in organic synthesis II. synthesis of verbena officinalis enol analogue

WU JIAJUN;TAO FENGGANG;XIAO SHOUJUN;WU SHIHUI   

  • Published:1986-12-25

本文对α-蒎烯与二氯卡宾的加成物3为原料,合成了马鞭草烯醇的类似物2,7,7-三甲基三环[4.1.1.0^2,^4]-5-辛醇及其酯类和醚类衍生物.

关键词: 碳烯, 辛醇 P, 有机合成, 昆虫激素, 烯醇, 蒎烯, 性引诱剂, 马鞭草, 多环烃

Verbenol analogs I and II were prepared starting from a-pinene. Thus, reaction of a-pinene with dichlorocarbene gave the adduct III. Reduction of III with Na/NH3 followed by ozone oxidation gave I, which was reduced with NaBH4 to II.

Key words: CARBENE, OCTANOL P, ORGANIC SYNTHESIS, INSECT HORMONE, ENOLS, PINENE, SEX ATTRACTANT, VERBENA OFFICINALIS, POLYCYCLIC HYDROCARBON

中图分类号: