有机化学 ›› 1988, Vol. 8 ›› Issue (1): 58-60. 上一篇    下一篇

研究论文

周环反应选择定则的一个推导

闵新民   

  1. 吉林大学理论化学研究所
  • 发布日期:1988-02-25

A deduction of selection rules of pericyclic reaction

MIN XINMIN   

  • Published:1988-02-25

研究了周环反应的反应历程, 并根据本征多项式的系数, 矩和总介电子能之间的关系推导出周环反应的选择定则.

关键词: 物理化学, 环化, 环加成反应, 特征函数, 电子能级, 共轭函数

Selection rules of concerted reactions are somewhat simply deduced from the relationships between coefficients of characteristic polynomials, moments and total p electron energy.d

Key words: PHYSICAL CHEMISTRY, CYCLIZATION, CYCLOADDITION REACTION, CHARACTERISTIC FUNCTIONS, ELECTRON ENERGY LEVEL, CONJUGATE FUNCTIONS

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