关键词: 催化, 环氧化反应, 钙化合物, 氢化物, 酒石酸 P, 钛化合物, 消旋体拆分, 硅胶, 丙氧基, 丙烯醇, 不对称反应

In the asym. epoxidn. of allylic alcs. with catalytic amount of Ti(OCHMe)4-diisopropyl tartrate and in the presence of catalytic amts. of calcium hydride (10%) and silica gel (15%), the reaction time was not significantly reduced. The epoxidn. of six primary allylic alcs. and the kinetic resoln. of dl-3-octen-2-ol are described.